Treatment of hydrogen chloride (gaseous HCl) and hydrochloric acid (liquid HCl)

Recuperación de ácido clorhídrico

GAB Neumann offers a complete range of processes in the field of hydrogen chloride (gaseous HCl) and hydrochloric acid (liquid HCl) treatment. It includes the absorption, cleaning, desorption, rectification, re-concentration (above the azeotropic point) and scrubbing of hydrochloric acid.

 

 

GAB Neumann offers the complete range of associated services including basic engineering, detail engineering, procurement, construction, project management, and start-up of these units.

Snapshots

Materials:

  • Impervious graphite: GAB GPX1, GPX1T or GPX2
  • Carbon Fiber Reinforced Carbon: CCX 190 or CCX 400
  • Pressure plates and flanges: carbon steel or stainless steel
  • Tie rods, nuts, bolts, washers, springs: stainless steel
  • PTFE lined steel, glass lined steel or FRP piping

Design:

  • Modular design: the different pieces of equipment (absorber, columns, reboiler, primary, secondary and tertiary condensers) of the system can be adapted (height, diameter, heat transfer surfaces, columns internals) to the process requirements.

Key Features:

  • Recovery of hydrochloric acid
  • Reconcentration above the azeotropic point
  • Generation of up to 2000 kg/h of gaseous pure dry HCl
  • Design pressure: -1 barg (full vacuum) to +10 barg (145 psig)
  • Design temperature: -60 to +200°C (-76 to 392°F)
  • Design:  according to European PED, ASME code, Chinese Pressure Vessel code or any other national pressure vessel code

Key Benefits:

  • Outstanding corrosion resistance
  • Superior heat transfer and mass transfer performances
  • Superior process equipment (absorber, fractioning column, reboiler and condensers) efficiency
  • Reboiler and condenser integrated in the graphite column
  • High operational safety
  • Sturdy and modular design
  • Short lead time
  • Long lifetime

Optional features:

  • Detail engineering with control and regulation
  • On-site erection and start-up
  • Carbon fiber reinforcement

Main applications:

  • Hydrochloric acid recovery
  • Generation of highly concentrated HCl
  • Generation of dry HCl

Adiabatic absorption of hydrogen chloride

Adiabatic absorption of hydrogen chloride can be easily achieved in a packed column. Gaseous hydrogen chloride enters at the bottom of the column while fresh water enters at the top and is distributed over the whole packing cross-section. The absorption process is exothermic (approximately 2100 kJ/kg of absorbed HCl) therefore the hydrochloric acid solution gets easily warm thus limiting the maximum concentration of the acid to approximately 31%.

 

Isothermal absorption of hydrogen chloride

The isothermal absorption of hydrogen chloride can be achieved in a packed column with an external recirculation and a cooler. The enthalpy of absorption is removed by the cooling water. A maximum concentration of 38% can be achieved this way.

 

 

The very same operation can be also achieved in a falling film absorber. 

 

Rectification of hydrochloric acid (aqueous HCl solution)

HCl solutions can be rectified both below and above the azeotropic point. Successive rectifications over different temperature ranges allow the separation of contaminants / pollutants such as fluorides, chlorides, bromides, iodides, organic compounds (volatile on non-volatile), salts, or solvents among others.

 

Production of anhydrous hydrogen chloride

Highly concentrated hydrogen chloride can be produced from 28 to 37% hydrochloric acid. Gaseous hydrogen chloride at more than 99% can be easily produced at the top of a rectification column. The HCl-rich vapors are then successively condensed in a series of condensers operating at colder and colder temperatures. The first condenser is cooled with cooling water. The second condenser is cooled with chilled water. Finally, the third condenser is cooled with brine or ethylene glycol. Finally, a knock-out drum prevents the entrainment of droplets. With this method, it is possible to produce hydrogen chloride with less than 50 ppm of moisture.

 

Concentration above the azeotropic point

The HCl / H2O mixture presents an azeotrope at a concentration of 20.3% (calculated using the Mixed Solvent Electrolyte model of OLI Systems, Incorporated) in weight at atmospheric pressure. The concentration processes consist of going around or displacing the azeotropic point.

 

Influence of pressure on the azeotrope

The concentration of the HCl / H2O azeotrope varies with the pressure. The HCl / H2O azeotrope is slightly less concentrated at high pressure than at low pressure. It is therefore possible to overcome the azeotropic barrier by transferring HCl / H2O azeotropes at two different concentrations between two columns at different pressures.

 

     

 

(* Calculated using the Mixed Solvent Electrolyte model of OLI Systems, Incorporated)

Dual-pressure process

The first rectification column operates under vacuum. Water is extracted at the top while the HCl / H2O azeotrope comes out at the bottom and is fed into the second column that operates above atmospheric pressure. In the second rectification column concentrated HCl is produced at the top while the HCl / H2O azeotrope comes out at the bottom and returns to the first column. Thanks to the lower operating pressure the azeotrope coming out at the bottom of the first rectification column has a "slightly" higher concentration (above 22%) than the azeotrope coming out at the bottom of the second rectification column (below 17%). Due to the necessity to go around the azeotrope, the whole rectification process is rather capital intensive and energy consuming.

 

Dual pressure process

Influence of extractive agents on the azeotrope

The relative volatility of the HCl can be changed by adding an extractive agent to the mixture. The change in volatility moves or even eliminates the azeotrope.

 

Extractive distillation process

The extractive distillation process involves the addition of an extractive agent with hygroscopic properties to shift or remove the azeotropic point and increase the volatility of HCl. Sulfuric acid (H2SO4) and calcium chloride (CaCl2) are the most commonly used extractive agents. The concentrated extractive agent enters an extractive / rectification column in graphite where it traps water. The diluted extractive agent leaves the column at the bottom before being re-concentrated. Highly concentrated HCl gas leaves the column at the top.

 

Scrubbing

Scrubbers are commonly used to remove traces of HCl and / or halogens (e.g. Cl2) in vents. They operate with an excess of absorption water therefore external cooling is not necessary. To neutralize the HCl, it is very common to use an aqueous sodium hydroxide (NaOH) solution as the scrubbing fluid.

 

 

Industrial processes:

  • Crop protection
  • Fumed silica
  • Silicones
  • Titanium dioxide
  • Fine chemicals
  • Active pharmaceutical ingredients
  • Epichlorohydrin
  • Vinyl chloride monomer
  • Flavors and fragrances
  • Vitamins
  • Isocyanates
  • Polycarbonate
  • Coagulants
  • Treatment, purification and concentration of spent acids
  • and many more…

GAB Neumann GmbH

Alemannenstrasse 29

79689 Maulburg

Germany

Tel: +49 (7622) 6751 0

Fax: +49 (7622) 6751 20

info@gab-neumann.de

GAB Neumann GmbH | Alemannenstrasse 29 | D-79689 Maulburg | Phone +49 (7622) 6751 0 | Fax +49 (7622) 6751 20 | E-Mail info@gab-neumann.de | www.gab-neumann.com

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